The Synthesis and Characterization of Some Transition Metal Complexes Prom Mixtures of Poly Pyrazolyl Borates
Date of Award
Master of Arts
Dr. Donald Brown
Dr. Ralph K. Steinhaus
Dr. Dean W. Cooke
Masters Thesis-Open Access
This is a report of the synthesis and separation of transition metal complexes of hydrotris(1-pyrazolyl)- borate and hydrotris(3,5-dimethyl-l-pyrazolyl)borate. These complexes contain a central metal ion and two tridentate ligands, one hydrotris(1-pyrazolyl)borate and one hydrotris(3,5-dimethyl-l-pyrazolyl)borate. Mass spectrometry proved to be an extremely useful technique for identifying products. Many mass spectra are included and discussed extensively.
Complexes containing hydrobis(pyrazole)(3,5-dimethyl -1-pyrazolyl)borate and hydrobis(3,5-dimethyl-l-pyrazole) (pyrazolyl)borate also were synthesised and mass spectra obtained.
Alway, Robert Matthew, "The Synthesis and Characterization of Some Transition Metal Complexes Prom Mixtures of Poly Pyrazolyl Borates" (1984). Masters Theses. 1457.